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Aflatoxins revisited: convergent synthesis of the ABC-moiety

Synthesis Journal of Synthetic Organic Chemistry (10): 760-763

Aflatoxins revisited: convergent synthesis of the ABC-moiety

After appropriate model studies, two methods of preparative interest, radical-initiated 5-exo-trig cyclization and palladium/formate anion mediated intramolecular hydroarylation, were confronted and optimised for the convergent synthesis of the oxygenated ABC-moiety of aflatoxin B1.

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Accession: 001748065

DOI: 10.1055/s-1988-27700

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