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Synthesis and characterization of a new series of zinc phosphites

Inorganic Chemistry 28(13): 2608-2615

Synthesis and characterization of a new series of zinc phosphites

Several new phosphites have been synthesized in aqueous solution by reactions of Zn2+ with H3PO3 and either Na+, K+, or Ba2+. The structures, determined by single-crystal X-ray diffraction techniques, are Zn(H2PO3)2.3H2O, Zn2(HPO3)2(H2O)4.H2O, Zn3Na3(HPO3)4, Zn3K2(HPO3)4, and Zn3Ba(HPO3)4(H2O)6.

Accession: 001962446

DOI: 10.1021/ic00312a021

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