EurekaMag.com logo
+ Site Statistics
References:
52,725,316
Abstracts:
28,411,598
+ Search Articles
+ Subscribe to Site Feeds
EurekaMag Most Shared ContentMost Shared
EurekaMag PDF Full Text ContentPDF Full Text
+ PDF Full Text
Request PDF Full TextRequest PDF Full Text
+ Follow Us
Follow on FacebookFollow on Facebook
Follow on TwitterFollow on Twitter
Follow on Google+Follow on Google+
Follow on LinkedInFollow on LinkedIn

+ Translate

Synthesis and characterization of a new series of zinc phosphites






Inorganic Chemistry 28(13): 2608-2615

Synthesis and characterization of a new series of zinc phosphites

Several new phosphites have been synthesized in aqueous solution by reactions of Zn2+ with H3PO3 and either Na+, K+, or Ba2+. The structures, determined by single-crystal X-ray diffraction techniques, are Zn(H2PO3)2.3H2O, Zn2(HPO3)2(H2O)4.H2O, Zn3Na3(HPO3)4, Zn3K2(HPO3)4, and Zn3Ba(HPO3)4(H2O)6.

Accession: 001962446

DOI: 10.1021/ic00312a021

Download PDF Full Text: Synthesis and characterization of a new series of zinc phosphites



Related references

Sutrisno, A.; Liu, L.; Xu, J.; Huang, Y., 2012: Natural abundance solid-state 67Zn NMR characterization of microporous zinc phosphites and zinc phosphates at ultrahigh magnetic field. Zinc-phosphite and -phosphate based microporous materials are crystalline open framework materials with potential industrial applications. Although (31)P MAS NMR has been used for characterization of these materials, the local environments around...

Schnabel, R.C.ris; Guida, W.C.; Kakoullis, J.J.; Thomas, T., 2003: Zinc metalloprotease model systems Synthesis and characterization of a series of zinc bis and tris imidazole complexes. Abstracts of Papers American Chemical Society 225(1-2): INOR 185

Wang, K.; Bian, Y.; Li, J.; Xu, D.; Lin, Z., 2016: Amine-Ligated Approach for the Synthesis of Extra-Large-Pore Zinc Phosphites with qtz-h and bnn Topologies. Presented here are two open-framework zinc phosphites, namely, Zn(dabco)0.5(HPO3) (SCU-18) and Zn4(Hdabco)2(CH3COO)2(HPO3)4 (SCU-20), where dabco = 1,4-diazabicyclo[2.2.2]octane. SCU-18 features a rare 3-connected inorganic skeleton with a chiral...

Mandal, S.; Natarajan, S., 2008: Synthesis, structure, and polymorphism studies in amine-templated open-framework zinc phosphites. Five new zinc phosphites, [C10N4H26][Zn2(HPO3)4].2H2O, 1, [C10N4H26][Zn5(H2O)4(HPO3)6].4H2O, 2, [C10N4H26][Zn4(HPO3)6].2H2O, 3, [C10N4H26][Zn4(HPO3)6].2H2O, 4, and [Zn2(HPO3)2(C10N4H24)], 5, were synthesized employing solvo/hydrothermal reactions...

Gaul, D.A.; Just, O.; Rees, W.S., 2001: Synthesis and characterization of a series of zinc bis[(alkyl)(trimethylsilyl)amide] compounds. A series of 21 secondary (alkyl)(trimethylsilyl)amines HNR(TMS) [R = n-propyl (1), i-propyl (2), n-butyl (3), i-butyl (4), s-butyl (5), tert-butyl (6), c-pentyl (7), n-pentyl (8), i-pentyl (9), l-methylbutyl (10), 2-methylbutyl (11), 1-ethylpropyl...

Toma, J.M.D.lla; Bergstrom, D.E., 1994: Transition metal labeling of oligodeoxyribonucleotides Synthesis and characterization of tungsten nucleoside phosphites. Journal of Organic Chemistry 59(9): 2418-2422

Nikolova, R.; Bojilova, A.; Rodios, N.A., 1998: Reaction of 3-bromobenzyl and 3-bromoacetyl coumarin with phosphites. Synthesis of some new phosphonates and phosphates in the coumarin series. The reaction of 3-(1-bromobenzyl)coumarin 3 with trialkyl phosphites afforded in good yields the corresponding dialkyl phosphonates 5, the Arbuzov reaction products. The interaction of trialkyl phosphites with 3-(omega-bromoacetyl)coumarin 4 gave...

Shieh, M.; Martin, K.J.; Squattrito, P.J.; Clearfield, A., 1990: New low-dimensional zinc compounds containing zinc-oxygen-phosphorus frameworks: two-layered inorganic phosphites and a polymeric organic phosphinate. Two new zinc phosphites, ZnCa(HPO3)2 (H2O)2 and ZnSr(HPO3)2(H2O)2 have been prepared by reaction of zinc chloride with either calcium or strontium phosphite in aqueous phosphorus acid. The compounds have been characterized by single-crystal X-ray...

Iuliano, A.; Facchetti, S.; Uccello-Barretta, G., 2006: Asymmetric induction by the cholestanic moiety on tropos species: synthesis and stereochemical characterization of bile acid-based biphenyl phosphites. Three different bile acid-derived biphenyl phosphites were synthesized, starting from cholic and deoxycholic acids and biphenol, and their stereochemical features were checked by CD and NMR spectroscopies. On the basis of the spectroscopic results...

Fernández, S.; Pizarro, J.L.; Mesa, J.L.; Lezama, L.; Arriortua, M.I.; Olazcuaga, R.; Rojo, T., 2001: Hydrothermal synthesis and structural characterization of the (C(n)H(2n+6)N(2)[Mn(3)(HPO(3))4] (n = 3-8) new layered inorganic-organic hybrid manganese(II) phosphites. Crystal structure and spectroscopic and magnetic properties of (C(3)H(12)N(2)[Mn(3)(HPO(3))4. The (C(n)H(2n+6)N(2))[Mn(3)(HPO(3))(4)] (n = 3-8) compounds have been prepared by hydrothermal synthesis and characterized by X-ray diffraction data and spectroscopic techniques. The crystal structure of (C(3)H(12)N(2))[Mn(3)(HPO(3))(4)] has been...