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Synthesis of the (2E, 4Z, 6E)-, (2E, 4E, 6E)- and (2E, 4E, 6Z)-tetraenol stems of the host-selective AK and AF toxins by hydrometallation


Tetrahedron Letters 30(32): 4299-4302
Synthesis of the (2E, 4Z, 6E)-, (2E, 4E, 6E)- and (2E, 4E, 6Z)-tetraenol stems of the host-selective AK and AF toxins by hydrometallation
Hydrozirconation and hydrostannation, together with Pd0 catalysed coupling, were used to make (2E, 4Z, 6E)-, (2E, 4E, 6E)- and (2E, 4E, 6Z)- tetraenol stems as synthetic intermediates of the host-selective plant toxins AK-II (previously isolated from Alternaria kikuchiana) and AF-IIc and AF-IIa (previously isolated from A. alternata).


Accession: 001962627



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