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Kinetics of the water gas shift reaction catalyzed by rhodium(III) chloride in aqueous picoline studied by use of a continuous-flow stirred reactor



Kinetics of the water gas shift reaction catalyzed by rhodium(III) chloride in aqueous picoline studied by use of a continuous-flow stirred reactor



Inorganic Chemistry 30(20): 3837-3842



The homogeneous water gas shift catalysis by RhCl3.3H2O in aqueous picoline solution was investigated using a continuous-flow stirred reactor. The catalysis rates had a nonlinear dependence on total Rh over the range 3-20 mM as well as a nonlinear dependence on PCO over the range 0.2-1.8 atm.

Accession: 002147927

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DOI: 10.1021/ic00020a013

Download PDF Full Text: Kinetics of the water gas shift reaction catalyzed by rhodium(III) chloride in aqueous picoline studied by use of a continuous-flow stirred reactor



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