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Optimization of a multielement sequential extraction method employing an experimental design approach for metal partitioning in soils and sediments

Santamaría-Fernández, R.; Moreda-Piñeiro, A.; Hill, S.J.

Journal of Environmental Monitoring: Jem 4(2): 330-336

2002

ISSN/ISBN: 1464-0325
PMID: 11993779
DOI: 10.1039/b110293c
Accession: 003871022
The optimization of a simple multi-element extraction method employing an experimental design approach is described. The method uses centrifugation to pass one extractant solution at varying pH through a contaminated soil sample. The nature and concentration of the acid, rate of centrifugation and time, number of sequential leachates and the ratio of extractant volume:sample weight have been studied in order to obtain the optimum conditions for extraction.

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Related References

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Ziegelhoeffer A.; De Jong J.W.; Ferrari R.; Turi Nagy L. 1998: Identification of radionuclide partitioning in soils and sediments: Determination of optimum conditions for the exchangeable fraction of the nIST standard sequential extraction protocol Applied Radiation and Isotopes 49(9-11): 1289-1293
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