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Nucleoside transformations part 3 transformation of inosine into 2 and 3 deoxy inosine and 2 3 anhydro inosine



Nucleoside transformations part 3 transformation of inosine into 2 and 3 deoxy inosine and 2 3 anhydro inosine



Justus Liebigs Annalen der Chemie (10): 1585-1596



Reaction of inosine with trimethyl orthoacetate, pivaloyl chloride/pyridine and tributyltin hydride leads, via intermediates, to 2'- and 3'-deoxyinosine. Treatment of the 3'-iodohypoxanthine derivative with sodium methoxide yields 2',3'-anhydroinosine which forms an N-3 .fwdarw. C-3' cyclonucleoside in aqueous solution.

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