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Oligo nucleotides and nucleotide peptides 32. elongation of the peptide and oligo nucleotide fragments in nucleotidyl p n peptides the effect of the fragment complication on the chemical properties of nucleotide peptides



Oligo nucleotides and nucleotide peptides 32. elongation of the peptide and oligo nucleotide fragments in nucleotidyl p n peptides the effect of the fragment complication on the chemical properties of nucleotide peptides



Bioorganicheskaya Khimiya 5(11): 1623-1632



By means of adding the amino acid or peptide esters to nucleotides (oligonucleotides) and elongating the peptide and oligonucleotide fragments in the nucleotidyl-(P .fwdarw. N)-amino acid, a number of esters of nucleotidyl (oligonucleotidyl)-(P .fwdarw. N)-amino acids (peptides) were synthesized, which serve as a model of natural nucleotidepeptides. Elongation of the peptide and oligonucleotide chains in nucleotidyl-(P .fwdarw. N)-amino acids stabilized the phosphoamidate bond against the acid and hydroxylamine action. Stability of the phosphoamidate bond depends not only on the length of the peptide and the nucleotide chains but also on their amino acid and nucleotide composition. The action of pronase, carboxypeptidase, pancreatic RNase and phosphodiesterase.sbd.the enzymes used most frequently for structure determination of natural nucleotidepeptides.sbd.was studied on the prepared model compounds and the products of their action were determined.

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