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On the experimental validity of recent developments of solvent shift theory



On the experimental validity of recent developments of solvent shift theory



Tetrahedron 32(17): 2105-2108



The validity of the equations reported by Amos and Burrows on solvent shifts was tested in several solvents of 7 different symmetrical compounds (acridine, phenazine, thianthrene, xanthene, xanthen-9-one, acridar, phenoxazine). The results confirm that their approximation introduced to simplify the interpretation of experimental data generally is not valid.

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