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Oxidative cleavage of the di sulfide bond of cystine by allyl iso thio cyanate



Oxidative cleavage of the di sulfide bond of cystine by allyl iso thio cyanate



Journal of Agricultural & Food Chemistry 30(3): 618-620



Interaction of isothiocyanate [a Brassica constituent] with L-cystine under mild conditions was studied in detail. Electrophilic attack of allyl isothiocyanate to cystine resulted in scission of the sulfide bond to give 2 thiazoline derivatives, 2-amino- and 2-(allylamino)-2-thiazoline-4-carboxylic acid, and their formation mechanisms were proposed.

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Accession: 006053205

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