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Paper chromatographic behavior of some tertiary amine pollutants and an attempt at structure activity correlation



Paper chromatographic behavior of some tertiary amine pollutants and an attempt at structure activity correlation



Journal of Liquid Chromatography 7(1): 207-218



Ascending paper chromatography of some pesticides and toxicants containing a tertiary amino group was performed to record their mobilities in acidic, basic and saline waters and some common organic solvents. Several binary separations of these pollutants were achieved: Amitrole was obtained from azobenzene, bavistin, calixin, 2,4-lutidine, 2,6-lutidine, N-ethylmorpholine, .beta.-picoline, .gamma.-picoline and quinoline; azo benzene came from bavistin, calixin, 2,4-lutidine, 2,6-lutidine, .beta.-picoline, .gamma.-picoline, pyridine and quinoline; bavistin came from 2,4-lutidine, 2,6-lutidine, .beta.-picoline, .gamma.-picoline and quinoline; quinoline came from 2,4-lutidine, 2,6-lutidine, .beta.-picoline, .gamma.-picoline and N-ethylmorpholine came from binary mixtures. An attempt at structure-activity correlation revealed that the physical forces responsible for the chromatographic behavior and the toxicity were almost identical, and the most important common physical interaction seemed to be H-bonding.

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