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Photochemistry of bertyadionol and related compounds


Tetrahedron 34(2): 233-240
Photochemistry of bertyadionol and related compounds
Irradiation of the macrocyclic diterpene bertyadionol [Bertya cupressoidea] resulted in a single photoisomer, the formation of which was rationalized in terms of a novel photorearrangement resulting in transannular bond formation. The structure of this photoproduct was elucidated by a combination of chemical and spectroscopic methods. Two related compounds, diterpene B and D, and their acetate derivatives when photolyzed underwent E .fwdarw. Z isomerization of the conjugated double bond and epimerization about 1 center of the cyclopropyl moiety.

Accession: 006110318

DOI: 10.1016/s0040-4020(01)93610-5

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