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Poly saccharides of tropical pasture herbage part 7 identification of a new pinitol galactoside from seeds of trifolium subterraneum subterranean clover and analysis of several pasture legume seeds for cyclo hexitols and their galactosides



Poly saccharides of tropical pasture herbage part 7 identification of a new pinitol galactoside from seeds of trifolium subterraneum subterranean clover and analysis of several pasture legume seeds for cyclo hexitols and their galactosides



Australian Journal of Chemistry 30(7): 1583-1590



A pinitol galactoside isolated from ethanol extracts of seeds of T. subterraneum was shown to be 1D-2-O-(.alpha.-D-galactopyranosyl)-4-O-methyl-chiro-inositol (1). The structure is based on successive periodate oxidation, borohydride reduction, hydrolysis and acetylation (Smith degradation), yielding the tetraacetate of 2-O-methyl-L-xylitol. The seeds of 39 pasture legumes from 13 different genera [Desmodium, Dolichos lablab, Centrosema, Glycine, Leucaena, Lotononis, Medicago, Macroptilium, Pueraria, Trifolium, Vigna and Stylosanthes] and 26 spp. were analyzed by gas chromatography for (1), myo-inositol, D-(+)-pinitol and galactinol.

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Accession: 006141302

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Polysaccharides of tropical pasture herbage. 7. Identification of a new pinitol galactoside from seeds of Trifolium subterraneum (subterranean clover) and analysis of several pasture legume seeds for cyclohexitols and their galactosides. Australian Journal of Chemistry 30(7): 1583-1590, 1977

Polysaccharides of tropical pasture herbage. VII. Identification of new pinitol galactoside from seeds of Trifolium subterraneum (subterranean clover) and analysis of several pasture legume seeds for cyclohexitols and their galactosides. Australian journal of chemistry: 30 (7) 1583-1590, 1977

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