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Preparation of mixed ligand copper ii complexes with uracil or 6 methyl uracil and glycyl glycine



Preparation of mixed ligand copper ii complexes with uracil or 6 methyl uracil and glycyl glycine



Chemical and Pharmaceutical Bulletin (Tokyo) 26(9): 2886-2889



Mixed ligand complexes containing uracil (U) and 6-methyluracil (MeU) were prepared. The complexation and coordination sites of the mixed ligand complexes, Cu(II)(GG [glycylglycyl]) (UH)-HBr .cntdot. 3/2H2O and cu(II)(GG)(6-MeUH)(HBr .cntdot. H2O, were discussed. The N atom N1 of uracil bases may be the coordination site; glycylglycine apparently behaves as a tridentate chelate.

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