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Recent synthetic applications of the kolbe electrolysis

Recent synthetic applications of the kolbe electrolysis

Chemistry & Physics of Lipids 24(4): 321-334

Kolbe electrolysis is an effective and simple method for coupling of carboxylates. Experimental conditions and substitutents in the carboxylate that favor dimerization are specified and representative preparative examples are given. Cross-coupling of carboxylates with half-esters of dicarboxylic acids affords an easy access to fatty acids; additive dimerization with butadiene yields unsaturated diesters. Recent applications of the Kolbe reaction are the preparation of 1,5-dienes by dimerization of .beta., .gamma.-unsaturated acids and the synthesis of pheromones, e.g., muscalure, looplure, brevicomin or disparlure by mixed coupling of unsaturated carboxylic acids with half-esters of dicarboxylic acids.

Accession: 006269796

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DOI: 10.1016/0009-3084(79)90117-8

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Related references

Some recent applications of the kolbe electrolysis in organic synthesis. Torii, S. Studies In Organic Chemistry, Vol. 30. Recent Advances In Electroorganic Synthesis; 1st International Symposium, Kurashiki, Japan, October 31-November 3, . Xxvi 475p. Elsevier Science Publishers B.v: Amsterdam, Netherlands; Kodansha Ltd: Tokyo, Japan (dist. In The Usa And Canada By Elsevier Science Publishing Co., Inc: New York, New York, Usa). Illus. 3-8, 1987

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