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Spectral properties of steroid hormones sapogenins and alkaloids in the chugaev reaction as function of their structure


, : Spectral properties of steroid hormones sapogenins and alkaloids in the chugaev reaction as function of their structure. Ukrainskii Biokhimicheskii Zhurnal 60(2): 88-92

Spectral characteristics of the products of the Chugaev reaction with steroid hormones, sapogenins and alkaloids are analyzed by spectrophotometry and fluorescent spectroscopy. They are established to be dependent on a degree of nonsaturation, position of double bonds, nature and position of substitutes in the molecule structure. The reaction is shown possible to be used for quantitative determiation of a number of steroids. The fluorescent spectroscopy application essentially increases sensitivity of the method.

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