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Syntheses of alpha c functionalized n nitrodialkylamines esters of alkylnitroaminomethanol and 1 alkylnitroaminoethanol

Syntheses of alpha c functionalized n nitrodialkylamines esters of alkylnitroaminomethanol and 1 alkylnitroaminoethanol

Liebigs Annalen der Chemie (8): 1494-1503

The .alpha.-acetoxynitramines 5 and 6, important derivatives for studying the biological properties of N-nitrodialkylamines 4 [mutagens and carcinogens], were synthesized, and the stability of the ester bond was investigated. The reaction of N-nitroalkylamines 7 with 1-halogenoethyl acetates 9, thought to afford 6, yielded the diazene N-oxides 10 as the main products.

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