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Synthesis of homo arginine and a homo arginyl tetra peptide amide

Synthesis of homo arginine and a homo arginyl tetra peptide amide

Justus Liebigs Annalen der Chemie (11): 2033-2037

A simplified synthesis of homoarginine (Har) is described. This amino acid was used to prepare the peptide Har-Gly-Phe-Phe-NH2. In this synthesis homoarginine was employed in the form of N.alpha.-Boc-NG-NO2-Har-ONp. With these protecting groups homoarginine can also be used for the preparation of other peptides. The sequence synthesized is homologous to the biologically active section Arg-Gly-Phe-Phe (position 22-25) of the insulin B-chain.

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