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The chemistry of tri carbonyl iron complexes of pre calciferol 2 and tachy sterol 2



The chemistry of tri carbonyl iron complexes of pre calciferol 2 and tachy sterol 2



Journal of the Chemical Society Perkin Transactions I (9): 1014-1017



Photolysis of ergosterol in the presence of pentacarbonyliron gave (tachysterol2)tricarbonyliron and (precalciferol2)-tricarbonyliron as major and minor products respectively. Oxidation of these complexes with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone gave (5E,7Z,22E)-9,10-secoergosta-1(10),5,7,9(11),22-pentaen-3.beta.-ol.

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