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The lowest singlet state of purine


, : The lowest singlet state of purine. Photochemistry and Photobiology 23(5): 365-368

The 1(.pi.* .rarw. n) transition of purine isolated in inert gas matrices is reported. The transition, which exhibits considerable vibronic structure, appears in the 290-330 nm region of the purine phosphoresence excitation spectrum on the long wavelength side of the 260 nm 1(.pi.* .rarw. .pi.) transition. The transition is analyzed and vibrational assignments for the 1(n, .pi.*) state are given.

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Accession: 006712324

PMID: 935268

DOI: 10.1111/j.1751-1097.1976.tb07261.x

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