+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Highly beta stereoselective glycosylation by use of 1 o acetyl 2 6 anhydro 2 thioglycosyl donor for synthesis of 2 6 dideoxy beta glycosides



Highly beta stereoselective glycosylation by use of 1 o acetyl 2 6 anhydro 2 thioglycosyl donor for synthesis of 2 6 dideoxy beta glycosides



Tetrahedron Letters 33(11): 1491-1494



Gycosylations of the 1-O-acetyl-2,6-anhydro-2-thio sugar 3 with alcohols in the presence of several Lewis acids in CH2Cl2 proceeded smoothly to give the corresponding .beta.-O-glycosides with high stereocontrol in high yields, and the selectivity of the glycosylation was highly independent on Lewis acids.

Please choose payment method:






(PDF emailed within 1 workday: $29.90)

Accession: 007400937

Download citation: RISBibTeXText


Related references

The use of 2 4 5 2 4 5 hexachlorobiphenyl 6 cb as an unmetabolizable lipophilic model compound. Pharmacology and Toxicology. 69(6): 410-415, 1991

1,6-anhydro-2, 3-di-O-benzyl-5C-[(R)-ethoxycarbonyl(hydroxy)methyl]-beta-L-altrofur ano se. Acta Crystallographica. Section C Crystal Structure Communications 56: 1168-1169, 2000

2,3,4,6-Tetra-O-benzoyl-beta-D-glucopyranosylisothiocyanate: An efficient reagent for the determination of enantiomeric purities of amino acids, beta-adrenergic blockers and alkyloxiranes by high-performance liquid chromatography using standard reversed-phase columns. Journal of Chromatography 633(1-2): 287-294, 1993

Novel glycosidase inhibitors. Abstracts of Papers American Chemical Society 212(1-2): CARB 54, 1996

Studies of the persistence of white clover (Trifolium repens L.) in pasture swards carried out in Pawlowice in 1971-1993. Instytut Zootechniki Biuletyn Informacyjny 32(1): 29-38, 1994

Syntheses and radiochemical studies of 99mTc-complexes of polydentate tris-amineoxime ligands. Journal of Labelled Compounds and Radiopharmaceuticals 43(14): 1335-1344, 2000

2-deoxy 5-azacytidine and fetal hemoglobin induction in sickle cell anemia. Blood 96(7): 2379-2384, 2000

1,6-Asymmetric induction in boron-mediated aldol reactions: Application to a practical total synthesis of (+)-discodermolide. Organic Letters 5(1): 35-38, 2003

On the specificity of mushroom pleurotus ostreatus and pleurotus spodoleucus extracts. Vox Sanguinis 29(3): 221-227, 1975

Stereoselective synthesis of 11Z-retinal by use of tricarbonyliron complex. Bioorganic and Medicinal Chemistry Letters 6(17): 2049-2052, 1996

Importance of the unsaturated fatty acyl group of phospholipids in their stimulatory role on rat adrenal mitochondrial steroidogenesis. Biochemistry 25(21): 6461-6466, 1986

Comparative structural analysis and kinetic properties of lactate dehydrogenases from the four species of human malarial parasites. Biochemistry 43(20): 6219-6229, 2004

One-pot reactions of 2,4-(dioxobutylidene)phosphoranes. Efficient synthesis of 4-(2-hydroxybenzoyl)salicylic acid derivatives and buta-1,3-diene-1,4-dicarboxylates. Tetrahedron 63(16): 3293-3301, 2007

Studies of the pharmacokinetics and toxicity of once daily bolus intravenous busulfan in non-human primates. Blood 86(10 Suppl. 1): 225A, 1995

Yield of Robusta poplar stands in Hungary. 1969