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Syntheses of pseudo alpha d glucopyranose and pseudo beta l idopyranose two optically active pseudohexopyranoses from d glucose by using stereoselective reductive deacetoxylation with sodium borohydride and cyclitol formation from nitrofuranose as key reactions



Syntheses of pseudo alpha d glucopyranose and pseudo beta l idopyranose two optically active pseudohexopyranoses from d glucose by using stereoselective reductive deacetoxylation with sodium borohydride and cyclitol formation from nitrofuranose as key reactions



Chemical & Pharmaceutical Bulletin 36(9): 3714-3717



Two optically active pseudo-hexopyranoses, pseudo-.alpha.-D-glucopyranose and pseudo-.beta.-L-idopyranose, have been synthesized from D-glycose by using stereoselective deacetoxylations with NaBH4 and cyclitol formations from nitrofuranose derivatives as key reactions.

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