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Synthesis, conformation of 3'- (tetrazole-2-yl) -3'-deoxythymidine and its 5-derivatives: Substrate properties of 3'- (tetrazole-3-yl) -3'-deoxythymidine 5'-triphosphate

Ostrovskii, V.A.; Studentsov, E.P.; Poplavskii, V.S.; Ivanova, N.V.; Gurskaya, G.V.; Zavodnik, V.E.; Jasko, M.V.; Semizarov, D.G.; Krayevsky, A.A.

Nucleosides and Nucleotides 14(6): 1289-1300

1995


DOI: 10.1080/15257779508010691
Accession: 009510674

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5'-O-Benzoyl-3'-(tetrazole-2"-yl)-3'-deoxythymidine and its 5"-substituted derivatives were obtained by the reaction of 5'-O-benzoyl-2, 3'-anhydrothymidine with triethylammonium salts of either tetrazole or 5-substituted tetrazoles. Debenzoylation of these compounds yielded 3'-(tetrazole-2"-yl)-3'-deoxythymidine and its 5"-derivatives. Structures of two of them were confirmed by X-ray analysis.

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