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Easy access to N-alkylation of N-unsubstituted (60)fulleropyrrolidines: reductive amination using sodium triacetoxyborohydride

Easy access to N-alkylation of N-unsubstituted (60)fulleropyrrolidines: reductive amination using sodium triacetoxyborohydride

Tetrahedron Letters 45(20): 3975-3978

(60)Fulleropyrrolidines were used as secondary amines to react with aldehydes through reductive animations to afford N-alkylated derivatives. In spite of the very weak base activity of the nitrogen atom of N-unsubstituted (60)fulleropyrrolidines, this method was found to be efficient at the aid of sodium triacetoxyborohydride. Several N-alkylated derivatives were synthesized and fully characterized. Copyright 2004 Elsevier Ltd.

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Accession: 011986168

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DOI: 10.1002/chin.200434110

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