Home
  >  
Section 26
  >  
Chapter 25,610

Sucrose: Precise Determination of Crystal and Molecular Structure by Neutron Diffraction

Brown, G.M.; Levy, H.A.

Science 141(3584): 921-923

1963

ISSN/ISBN: 0036-8075
PMID: 14043338
DOI: 10.1126/science.141.3584.921
Accession: 025609344
Download citation:  
Text
  |  
BibTeX
  |  
RIS
This analysis provides the first precise molecular parameters for sucrose. All hydrogen atoms are included. Carbon-carbon distances are 1.51 1.53 A; carbon-oxygen 1.40 to 1.44 A; carbon-hydrogen 1.08 to 1.11 A; oxygen-hydrogen 0.94 to 0.99 A. The furanose ring conformation differs from that in sucrose sodium bromide dihydrate. Hydrogen bonds (two of them intramolecular) utilize every hydroxyl group except one.

PDF emailed within 0-6 h: $19.90




Related References

Levy, H.A. 1965: D-Glucose Precise determination of crystal and molecular structure by neutron-diffraction analysis Science 661: 1038-1039
Brown, G.M.; Levy, H.A. 1965: Alpha-D-Glucose: Precise Determination of Crystal and Molecular Structure by Neutron-Diffraction Analysis Science 147(3661): 1038-1039
Koetzle, T.F.; Lehmann, M.S.; Hamilton, W.C. 1973: Precision neutron diffraction structure determination of protein and nucleic acid components part 9 the crystal and molecular structure of 4 hydroxy l proline Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 29(2): 231-236
Lehmann, M.S.; Koetzle, T.F.; Hamilton, W.C. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components. IV. the crystal and molecular structure of the amino acid L-histidine International Journal of Peptide and Protein Research 4(4): 229-239
Lehmann, M.S.; Koetzle, T.F.; Hamilton, W.C. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components. I. the crystal and molecular structure of the amino acid L-alanine Journal of the American Chemical Society 94(8): 2657-2660
Filabozzi, A.; Buontempo, U.; Delaplane, R.; Ricci, F.P. 1994: A new precise determination of the liquid bromine structure by means of neutron diffraction Molecular Physics 82(3): 427-437
Koetzle, T.F.; Frey, M.N.; Lehmann, M.S.; Hamilton, W.C. 1973: Precision neutron diffraction structure determination of protein and nucleic acid components part 13 molecular and crystal structure of the amino acid l glutamine Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 29(11): 2571-2575
Jonsson P G.; Kvick, A. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components part 3 the crystal and molecular structure of the amino acid alpha glycine Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 28(6): 1827-1833
Cheetham, A.K.; David, W.I.F.; Eddy, M.M.; Jakeman, R.J.B.; Johnson, M.W.; Torardi, C.C. 1986: Crystal structure determination by powder neutron diffraction at the spallation neutron source, ISIS Nature (London) 320(6057): 46-48
Mogens, S. Lehmann; Thomas, F. Koetzle; Walter, C. Hamilton 1972: Precision neutron diffraction structure determination of protein and nucleic acid components. VIII: the crystal and molecular structure of the β-form of the amino acidl-glutamic acid Journal of Chemical Crystallography 2(5-6): 225-233
Verbist, J.J.; Lehmann, M.S.; Koetzle, T.F.; Hamilton, W.C. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components part 6 the crystal and molecular structure of the amino acid l asparagine mono hydrate Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 28(10): 3006-3013
Jones, D.D.; Bernal, I.; Frey, M.N.; Koetzle, T.F. 1974: Precision neutron diffraction structure determination of protein and nucleic acid components part 14 crystal and molecular structure of the amino acid l cystine di hydro chloride Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 30(5): 1220-1227
Koetzle, T.F.; Lehmann, M.S.; Verbist, J.J.; Hamilton, W.C. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components part 7 the crystal and molecular structure of the amino acid l lysine mono hydro chloride di hydrate Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 28(11): 3207-3214
Parthasarathy, R. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components part 2 the crystal and molecular structure of the di peptide glycyl glycine mono hydro chloride mono hydrate Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry: 2083-2090
Howard, J.A.K.; Johnson, O.; Koetzle, T.F.; Spencer, J.L. 1987: Crystal and molecular structure of bis(diisopropylphenylphosphine)hexahydridoosmium, [OsH6(PC12H19)2]: single-crystal neutron diffraction study at 20 K Inorganic Chemistry 26(18): 2930-2933