Home
  >  
Section 31
  >  
Chapter 30,790

D-Glucose Precise determination of crystal and molecular structure by neutron-diffraction analysis

Levy, H.A.

Science 661: 1038-1039

1965

ISSN/ISBN: 0091-7729
Accession: 030789398
Download citation:  
Text
  |  
BibTeX
  |  
RIS
This analysis provides the first precise crystal and molecular structural parameters for [alpha]-D-glucose. The C-C, C-H, and O-H bond lengths deviate only slightly from their means of 1.523 A, 1.098 A, and 0.968 A. The C(I)-O(I) bond length, 1.389 A, is significantly shorter than the mean value, 1.420 A, of the other C-O bonds. The valence angle of the ring oxygen is 113.8 degrees.

PDF emailed within 1 workday: $29.90




Related References

Brown, G.M.; Levy, H.A. 1965: Alpha-D-Glucose: Precise Determination of Crystal and Molecular Structure by Neutron-Diffraction Analysis Science 147(3661): 1038-1039
Brown, G.M.; Levy, H.A. 1963: Sucrose: Precise Determination of Crystal and Molecular Structure by Neutron Diffraction Science 141(3584): 921-923
Koetzle, T.F.; Lehmann, M.S.; Hamilton, W.C. 1973: Precision neutron diffraction structure determination of protein and nucleic acid components part 9 the crystal and molecular structure of 4 hydroxy l proline Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 29(2): 231-236
Moore, F.M.; Willis, B.T.; Hodgkin, D.C. 1967: Structure of a monocarboxylic acid derivative of vitamin B 12. Crystal and molecular structure from neutron diffraction analysis Nature 214(5084): 130-133
Lehmann, M.S.; Koetzle, T.F.; Hamilton, W.C. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components. IV. the crystal and molecular structure of the amino acid L-histidine International Journal of Peptide and Protein Research 4(4): 229-239
Lehmann, M.S.; Koetzle, T.F.; Hamilton, W.C. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components. I. the crystal and molecular structure of the amino acid L-alanine Journal of the American Chemical Society 94(8): 2657-2660
Filabozzi, A.; Buontempo, U.; Delaplane, R.; Ricci, F.P. 1994: A new precise determination of the liquid bromine structure by means of neutron diffraction Molecular Physics 82(3): 427-437
Koetzle, T.F.; Frey, M.N.; Lehmann, M.S.; Hamilton, W.C. 1973: Precision neutron diffraction structure determination of protein and nucleic acid components part 13 molecular and crystal structure of the amino acid l glutamine Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 29(11): 2571-2575
Jonsson P G.; Kvick, A. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components part 3 the crystal and molecular structure of the amino acid alpha glycine Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 28(6): 1827-1833
Cheetham, A.K.; David, W.I.F.; Eddy, M.M.; Jakeman, R.J.B.; Johnson, M.W.; Torardi, C.C. 1986: Crystal structure determination by powder neutron diffraction at the spallation neutron source, ISIS Nature (London) 320(6057): 46-48
Jones, D.D.; Bernal, I.; Frey, M.N.; Koetzle, T.F. 1974: Precision neutron diffraction structure determination of protein and nucleic acid components part 14 crystal and molecular structure of the amino acid l cystine di hydro chloride Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 30(5): 1220-1227
Verbist, J.J.; Lehmann, M.S.; Koetzle, T.F.; Hamilton, W.C. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components part 6 the crystal and molecular structure of the amino acid l asparagine mono hydrate Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 28(10): 3006-3013
Mogens, S. Lehmann; Thomas, F. Koetzle; Walter, C. Hamilton 1972: Precision neutron diffraction structure determination of protein and nucleic acid components. VIII: the crystal and molecular structure of the β-form of the amino acidl-glutamic acid Journal of Chemical Crystallography 2(5-6): 225-233
Ziegelhoeffer A.; De Jong J.W.; Ferrari R.; Turi Nagy L. 1986: Neutron diffraction analysis at 15 K and ab initio molecular orbital calculations for α-cyanoacetohydrazide: A crystal structure with a high energy conformer Journal of Molecular Structure 147(3-4): 369-380
Koetzle, T.F.; Lehmann, M.S.; Verbist, J.J.; Hamilton, W.C. 1972: Precision neutron diffraction structure determination of protein and nucleic acid components part 7 the crystal and molecular structure of the amino acid l lysine mono hydro chloride di hydrate Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 28(11): 3207-3214