+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Novel tandem ring-opening/ring-closing metathesis reactions of functionalized cyclohexenoids derived from -alpha-pinene

Novel tandem ring-opening/ring-closing metathesis reactions of functionalized cyclohexenoids derived from -alpha-pinene

Tetrahedron Letters 43(4): 699-702, 21 January

The cyclohexenone (+)-2, readily obtained from (-)-alpha-pinene 1 was elaborated to (+)-3 in an attempt to construct the AB rings of taxoids employing the ring-closure metathesis (RCM) reaction as the key step. In the event, a novel ring-opening/ring-closing metathesis reaction was encountered in the relatively strain free cyclohexenyl ring of (+)-3.

Please choose payment method:

(PDF emailed within 1 workday: $29.90)

Accession: 035410595

Download citation: RISBibTeXText

Related references

Tandem Ring-Opening-Ring-Closing Metathesis for Functional Metathesis Catalysts. Angewandte Chemie 55(40): 12343-6, 2016

The tandem ring opening/ring closing metathesis route to oxaspirocycles: an approach to phelligridin G. Molecules 18(2): 2438-2448, 2013

Tandem ring-opening/ring-closing metathesis polymerization: relationship between monomer structure and reactivity. Journal of the American Chemical Society 135(29): 10769-10775, 2013

Unsymmetrical Ru-NHC catalysts: a key for the selective tandem ring opening-ring closing alkene metathesis (RO-RCM) of cyclooctene. Dalton Transactions 40(46): 12443-6, 2011

Fast tandem ring-opening/ring-closing metathesis polymerization from a monomer containing cyclohexene and terminal alkyne. Journal of the American Chemical Society 134(17): 7270-7273, 2012

Synthesis of a highly functionalized tricyclic ring system related to guanacastepene via a tandem ring-closing metathesis reaction. Tetrahedron Letters 43(42): 7469-7472, 14 October, 2002

Ruthenium-catalyzed tandem ring-opening/ring-closing/cross-metathesis of 1,6-cyclopropene-ynes and olefins for the construction of the 3-pyrroline skeleton. Organic Letters 12(20): 4462-4465, 2010

Ring-opening/ring-closing metathesis (RORCM) reactions of 7-Azanorbornene derivatives. An entry into perhydroindolines. Organic Letters 8(3): 459-462, 2006

Supported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization. Polymers 8(4), 2019

Versatile Tandem Ring-Opening/Ring-Closing Metathesis Polymerization: Strategies for Successful Polymerization of Challenging Monomers and Their Mechanistic Studies. Journal of the American Chemical Society 138(7): 2244-2251, 2016

Domino ring-opening metathesis-ring-closing metathesis of bicyclo[2.2.2]octene derivatives: scope and limitations. Journal of Organic Chemistry 77(14): 6345-6350, 2012

Catalytic surfactants for ring-opening metathesis polymerization and ring-closing metathesis in non-degassed micellar solutions. Journal of Molecular Catalysis A: Chemical 263(1-2): 39-47, 2007

Phase transfer reagent promoted tandem ring-opening and ring-closing reactions of unique 3-(1-alkynyl) chromones. Organic Letters 17(9): 2134-2137, 2015

Synthesis of Pyrrolizidine, Indolizidine, and Quinolizidine Derivatives Using Ruthenium-Catalyzed Ring-Opening Metathesis and Ring-Closing Metathesis of Cycloalkene-ynes. Advanced Synthesis & Catalysis 349(7): 1231-1246, 2007

Bidirectional cross metathesis and ring-closing metathesis/ring opening of a C 2-symmetric building block: a strategy for the synthesis of decanolide natural products. Beilstein Journal of Organic Chemistry 9: 2544-2555, 2013