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Cyclic peroxides from a soya lipoxygenase-catalysed oxygenation of methyl linolenate

Cyclic peroxides from a soya lipoxygenase-catalysed oxygenation of methyl linolenate

Biochimica et Biophysica Acta 528(1): 119-126

Incubation of methyl linolenate with an aqueous extract of soyabean flour at neutral pH gives the hydroperoxyendoperoxides 16-hydroxyperoxy-13,15-endoperoxylinolenate and 9-hydroxyperoxy-10,12-endoperoxylinolenate as the principal oxygenation products in addition to monohydroperoxides. Lipoxygenase I (EC does not catalyse the oxygenation under this condition. The enzyme contributing most to the formation of the hydroperoxyendoperoxides is assumed to be a high molecular mass lipoxygenase aggregate.

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Accession: 038926993

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PMID: 23169

DOI: 10.1016/0005-2760(78)90057-7

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