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The synthesis of cholesteryl alkyl ethers

The synthesis of cholesteryl alkyl ethers

Steroids 35(1): 39-42

Seventeen cholesteryl alkyl ethers were synthesized through alcoholysis of cholesterol p-toluenesulfonate. This method was found superior to the etherification of sodium or potassium cholesterylate with alkyl halides or methanesulfonates, especially for the preparation of long-chain unsaturated aklyl ethers of [7(m)-3H]cholesterol of high specific activity.

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Accession: 044762590

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PMID: 7376210

DOI: 10.1016/0039-128x(80)90109-9

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