+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

A new class of single-molecule magnet: [Mn9O7(OAc)11(thme)(py)3(H2O)2] with an S = 17/2 ground state

A new class of single-molecule magnet: [Mn9O7(OAc)11(thme)(py)3(H2O)2] with an S = 17/2 ground state

Chemical Communications 2002(19): 2252-2253

The reaction of [Mn3O(OAc)6(py)3] with 1,1,1-tris(hydroxymethyl)ethane (H3thme) gives the Mn(IV)3Mn(III)4Mn(II)2 complex [Mn9O7(OAc)11(thme)(py)3(H2O)2], which has an S = 17/2 ground state and displays strong out-of-phase signals in ac susceptibility studies that establish it as a new class of single-molecule magnet.

Please choose payment method:

(PDF emailed within 0-6 h: $19.90)

Accession: 045079451

Download citation: RISBibTeXText

PMID: 12398002

DOI: 10.1039/b206386g

Related references

Single-chain magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of Mn(III)-Fe(III)-Mn(III) trinuclear single-molecule magnet with an S(T) = 9/2 spin ground state. Journal of the American Chemical Society 127(9): 3090-3099, 2005

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state. Chemical Communications 48(9): 1218-1220, 2011

The first {Dy4} single-molecule magnet with a toroidal magnetic moment in the ground state. Inorganic Chemistry 51(3): 1233-1235, 2012

Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe5CoMo22As2O85(H2O)]15-. Dalton Transactions 42(1): 58-62, 2013

"Spin tweaking" of a high-spin molecule: an Mn25 single-molecule magnet with an S=61/2 ground state. Angewandte Chemie 46(6): 884-888, 2006

A Ferromagnetic Salicylaldoximate/Azide Mn(II)2Mn(III)6 Cluster with an S = 17 Ground State and a Single-Molecule-Magnet Response. Inorganic Chemistry 55(12): 5735-5737, 2016

Effects of chemically induced contraction of a coordination polyhedron on the dynamical magnetism of bis(phthalocyaninato)disprosium, a single-4f-ionic single-molecule magnet with a Kramers ground state. Inorganic Chemistry 47(22): 10217-9, 2008

DFT computational rationalization of an unusual spin ground state in an Mn12 single-molecule magnet with a low-symmetry loop structure. Angewandte Chemie 44(6): 897-901, 2004

From an S(T) = 3 single-molecule magnet to diamagnetic ground state depending on the molecular packing of Mn(III)salen-type dimers decorated by N,N'-dicyano-1,4-naphthoquinonediiminate radicals. Inorganic Chemistry 45(11): 4381-4390, 2006

A single molecule magnet to single molecule magnet transformation via a solvothermal process: Fe4Dy2 → Fe6Dy3. Dalton Transactions 45(1): 98-106, 2015

MnIII2 (5-Rsaltmen)2NiII(pao)2(L)]2+: an S(T)=3 building block for a single-chain magnet that behaves as a single-molecule magnet. Chemistry 11(5): 1592-1602, 2005

Effect of structural isomerism on magnetic dynamics: from single-molecule magnet to single-chain magnet. Inorganic Chemistry 53(6): 3117-3125, 2014

A new versatile class of hetero-tetra-metallic assemblies: highlighting single-molecule magnet behaviour. Chemical Communications 49(82): 9476-9478, 2013

Neutron-diffraction evidence for the ferrimagnetic ground state of a molecule-based magnet with weakly coupled sublattices. Journal of Physics. Condensed Matter 24(49): 496001, 2012

Achiral single molecule magnet and chiral single chain magnet. Chemical Communications 46(33): 6117-6119, 2010