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A new class of single-molecule magnet: [Mn9O7(OAc)11(thme)(py)3(H2O)2] with an S = 17/2 ground state



A new class of single-molecule magnet: [Mn9O7(OAc)11(thme)(py)3(H2O)2] with an S = 17/2 ground state



Chemical Communications 2002(19): 2252-2253



The reaction of [Mn3O(OAc)6(py)3] with 1,1,1-tris(hydroxymethyl)ethane (H3thme) gives the Mn(IV)3Mn(III)4Mn(II)2 complex [Mn9O7(OAc)11(thme)(py)3(H2O)2], which has an S = 17/2 ground state and displays strong out-of-phase signals in ac susceptibility studies that establish it as a new class of single-molecule magnet.

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Accession: 045079451

Download citation: RISBibTeXText

PMID: 12398002

DOI: 10.1039/b206386g


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