+ Translate
+ Most Popular
Investigations on the organic drift in North Swedish streams
Limitations of Using Microsoft Excel Version 2016 (MS Excel 2016) for Statistical Analysis for Medical Research
Phloem necrosis of coffee in Surinam
Anatomy of Mystus seenghala IV Nervous system
Integrated farming system for gardenland conditions of Coimbatore district - an over view
Tetrapleure (Tetrapleura tetraptera), an unknown African medicinal and spice plant
The origin and phylogenetic significance of the trochophoran larvae 2. evolutionary significance of the larvae of coelomate worms and mollusks
Comparison of rice bran and maize bran as feeds for growing and fattening pigs
Enterobacter amnigenus. An unusual human pathogen
Influence of Seriboost foliar application on leaf yield and leaf protein content in mulberry (Morus spp.), in relation to silkworm cocoon production
The identity of the lipstick mold of cultivated mushrooms agaricus bisporus
Advantages and disadvantages of bordeaux mixture and of lime-sulphur used on apples in the growing season
'Pan-sukh' disease of Rice in the Central Provinces
Geological age of the Ptilophyllum flora; a critical reassessment
Study of vitellogenesis in birds; physiological phases & role of folliculin in vitellogenesis
Evaluation of WCT coconut and Komadan coconut
Therapy for acne with saccharomyces boulardii
Evidence for Late Cretaceous N-S dextral shear in the west-central crystalline core, North Cascades, Washington
'Rajeshwari' - a high-yielding white seeded variety of sesame for Andhra Pradesh
Manufacture of Ricotta cheese from whey fortified with skim milk powder using different acidulants
Occurrence of Eutrichophilus mexicanus (Rudow, 1866) and Eutrichophilus lobatus (Ewing, 1936) (Phthiraptera: Trichodectidae) on Sphiggurus villosus (Cuvier, 1825) (Rodentia: Erethizontidae) in Rio de
Factors affecting fruitfulness in durian (Durio zibethinus Murr.). I. Flowering and pollination
Bronchial cuff pressure change caused by left-sided double-lumen endobronchial tube displacement
Some Biological Applications of Organometallic Compounds
The composition of pampas-grass (Cortaderia argentea.)

Is water a friend or foe in organometallic chemistry? The case of group 13 organometallic compounds

Is water a friend or foe in organometallic chemistry? The case of group 13 organometallic compounds

Accounts of Chemical Research 34(3): 201-211

ISSN/ISBN: 0001-4842

PMID: 11263878

DOI: 10.1021/ar0001158

This Account summarizes the recent developments in the hydrolysis chemistry of Group 13 trialkyl and triaryl compounds. Emphasis has been placed on the results obtained by us on (a) 1H NMR investigations of controlled hydrolyses of AlMes3 and GaMes3, (b) low-temperature isolation of water adducts of triaryl compounds of aluminum and gallium, (c) synthesis and structural characterization of new polyhedral alumoxanes and galloxanes, and (d) the search for an easy way to synthesize well-defined crystalline methylalumoxanes by deprotonation of the hydroxides with alkyllithium reagents. The systematic studies on the hydrolysis of tBu3Al carried out by Barron et al. are also discussed in order to elucidate the roles of (i) reaction temperature, (ii) solvent medium, and (iii) source of water molecules, in building up hitherto unknown alumoxane clusters. The role of water impurity in organometallic reactions involving a Group 13 alkyl and other ligands (such as silanetriols and phosphorus acids) to build molecular clusters has also been discussed.

Please choose payment method:

(PDF emailed within 0-6 h: $19.90)

Accession: 046481668

Download citation: RISBibTeXText

Related references

Removal of organometallic compounds from natural feedstock by surface organometallic chemistry on metals: hydrogenolysis of AsPh3 on nickel supported on alumina. Comptes Rendus de L'académie des Sciences - Series Iic - Chemistry 3(6): 423-427, 2000

Chemiluminescence testing of solutions to detect organometallic peroxides during oxidation of organometallic compounds by oxygen. Russian Chemical Bulletin 35(10): 2022-2024, 1986

Radical steps in the reactions of organometallic compounds with 2-methyl-2-nitrosopropane: experimental evaluation of the validity of the nitroxyl method for investigations of homolytic reactions of organometallic compounds. Russian Chemical Bulletin 43(5): 862-866, 1994

Organometallic geochemistry; 2, The molecular characterization of trace organometallic and inorganic compounds of arsenic found in Green River Formation oil shale and its pyrolysis product. Energy and Fuels 1(3): 243-247, 1987

The Chemistry of organometallic compounds. 1957

Organometallic compounds in biological chemistry. Abel, E W And F G A Stone A Specialist Periodical Report: Organometallic Chemistry, Vol 13 A Review Of The Literature Published During 1983 Xv+491p The Royal Society Of Chemistry: London, England Illus 381-406, 1985

Organometallic synthesis and chemistry of tin and lead compounds. Microchimica Acta 109(1-4): 5-12, 1992

Organometallic compounds in nucleic acid chemistry. LA-3610-MS. La Reports . U.S. Atomic Energy Commission 1966: 135-137, 1966

The chemistry of inorganic and organometallic compounds with adamantane-like structures. Polyhedron 15(10): 1585-1642, 1996

Organometallic chemistry in water. Current Science 63(9-10): 547-550, 1992

Organometallic compounds of the lanthanideXL. Recent developments in organolanthanide chemistry. Polyhedron 7(22-23): 2307-2315, 1988

Chemistry of organometallic compounds on silicon: the first step in film growth. Chemistry 13(33): 9164-9176, 2007

Organometallic chemistry part ii main group elements. Gill, G B And D A Whiting Annual Reports on The Progress Of Chemistry Section B Organic Chemistry, Vol 86 Xiv+348p Royal Society Of Chemistry: Cambridge, England, Uk Illus 261-284, 1989

Some Applications of Organosilicon and Organotin Compounds as Synthetic Intermediates in Organometallic Chemistry. Annals of the new York Academy of Sciences 239(1): 306-314, 1974

The chemistry of selenium-bearing organometallic derivatives of group VA elements. Annals of the new York Academy of Sciences 192: 72-89, 1972