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Metathesis route to bridged metallocenes

Metathesis route to bridged metallocenes

Journal of the American Chemical Society 124(31): 9068-9069

A variety of bridged metallocenes of Fe(II), Ru(II), Zr(IV), or Hf(IV) were prepared in good yield by the interannular ring-closing metathesis reaction of 1,1'-diallylmetallocenes using the Ru-carbene catalyst, and the present method was extended to diastereoselective reaction to give dl- or meso-bridged metallocenes with excellent stereoselectivity.

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Accession: 046673081

Download citation: RISBibTeXText

PMID: 12149008

DOI: 10.1021/ja028166i

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