+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Catalytic C=N bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands

Catalytic C=N bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands

Chemical Communications 2003(20): 2612-2613

A family of guanidinate-supported imido metal complexes are novel, effective catalysts for C=N metathesis of alkyl and aryl carbodiimides and evidence suggests that this reaction proceeds via a sequential addition/elimination pathway.

Please choose payment method:

(PDF emailed within 0-6 h: $19.90)

Accession: 048464048

Download citation: RISBibTeXText

PMID: 14594306

DOI: 10.1039/b308710g

Related references

Terminal cobalt(III) imido complexes supported by tris(carbene) ligands: imido insertion into the cobalt-carbene bond. Journal of the American Chemical Society 126(50): 16322-3, 2004

Synthesis and X-ray crystal structures of imido and ureato derivatives of titanium(IV) phthalocyanine and their application in the catalytic formation of carbodiimides by metathesis from isocyanates. Dalton Transactions 40(8): 1787-1794, 2011

Group 6 imido complexes supported by diamido-donor ligands. Inorganic Chemistry 42(16): 4961-4969, 2003

Postmetallocene lanthanide-hydrido chemistry: A new family of complexes [{Ln{(Me3Si)2NC(NiPr)2}2(mu-H)}2] (Ln = Y, Nd, Sm, Gd, Yb) supported by guanidinate ligands-synthesis, structure, and catalytic activity in olefin polymerization. Chemistry 12(20): 5320-5327, 2006

Reactivity of a titanium dinitrogen complex supported by guanidinate ligands: investigation of solution behavior and a novel rearrangement of guanidinate ligands. Inorganic Chemistry 40(27): 6952-6963, 2001

Alkane metathesis catalyzed by a well-defined silica-supported Mo imido alkylidene complex: [(triple bond SiO)Mo(=NAr)(=CHtBu)(CH2tBu). Angewandte Chemie 45(37): 6201-6203, 2006

Well-defined silica-supported zirconium-imido complexes mediated heterogeneous imine metathesis. Chemical Communications 52(25): 4617-4620, 2016

Synthesis, structures of mononuclear and dinuclear iron(II) complexes supported by non-symmetric guanidinate(amidinate) ligands. Polyhedron 141: 100-104, 2018

Quantitatively analyzing metathesis catalyst activity and structural features in silica-supported tungsten imido-alkylidene complexes. Journal of the American Chemical Society 137(20): 6699-6704, 2015

Trinuclear alkyl hydrido rare-earth complexes supported by amidopyridinato ligands: synthesis, structures, C-Si bond activation and catalytic activity in ethylene polymerization. Dalton Transactions 43(38): 14450-14460, 2014

Non-innocent behaviour of imido ligands in the reactions of silanes with half-sandwich imido complexes of Nb and V: a silane/imido coupling route to compounds with nonclassical Si--H interactions. Chemistry 14(1): 296-310, 2008

Catalytic C-H bond amination from high-spin iron imido complexes. Journal of the American Chemical Society 133(13): 4917-4923, 2011

Macrocycle-supported titanium complexes with chelating imido ligands: analogues of ansa-metallocenes. Inorganic Chemistry 39(24): 5483-5491, 2000

Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes. Journal of the American Chemical Society 138(1): 52-55, 2016

Activation of carbodiimide and transformation with amine to guanidinate group by Ln(OAr)3(THF)2 (Ln: lanthanide and yttrium) and Ln(OAr)3(THF)2 as a novel precatalyst for addition of amines to carbodiimides: influence of aryloxide group. Inorganic Chemistry 50(8): 3729-3737, 2011