+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Condensed phase behaviour of ionic liquid-benzene mixtures: congruent melting of a [emim][NTf2].C6H6 inclusion crystal



Condensed phase behaviour of ionic liquid-benzene mixtures: congruent melting of a [emim][NTf2].C6H6 inclusion crystal



Chemical Communications 2006(23): 2445-2447



The solid-liquid phase diagram of the (1-ethyl-3-methylimidazolium bis{(trifluoromethyl) sulfonyl} amide + benzene) system was determined and allowed us to identify and characterize an equimolar inclusion compound, [emim][NTf2].C6H6, with a congruent melting temperature: this type of behaviour, reported here for the first time, together with the X-ray structure of the inclusion compound lays emphasis upon the interactions that are responsible for the existence of liquid clathrates at higher benzene concentrations.

Please choose payment method:






(PDF emailed within 0-6 h: $19.90)

Accession: 048622753

Download citation: RISBibTeXText

PMID: 16758010

DOI: 10.1039/b602675c


Related references

Molecular dynamics study of congruent melting of the equimolar ionic liquid-benzene inclusion crystal [emim][NTf(2)].C(6)H(6). Journal of Chemical Physics 132(4): 044507, 2010

Binary diffusion coefficients for mixtures of ionic liquids [EMIM][N(CN)2], [EMIM][NTf2], and [HMIM][NTf2] with acetone and ethanol by dynamic light scattering (DLS). Journal of Physical Chemistry. B 117(8): 2429-2437, 2013

Density, refractive index, interfacial tension, and viscosity of ionic liquids [EMIM][EtSO4], [EMIM][NTf2], [EMIM][N(CN)2], and [OMA][NTf2] in dependence on temperature at atmospheric pressure. Journal of Physical Chemistry. B 112(39): 12420-12430, 2008

Improvement of the Co 2 Absorption Performance Using Ionic Liquid [Nh 2 emim][Bf 4 ] and [emim][Bf 4 ]/[bmim][Bf 4 ] Mixtures. Energy & Fuels 27(1): 461-466, 2013

Modeling of the volumetric properties and estimation of the solubility parameters of ionic liquid+ethanol mixtures with the SanchezLacombe and SimhaSomcynsky equations of state: [Emim]Ac+ethanol and [Emim]Cl+ethanol mixtures. The Journal of Supercritical Fluids 98: 86-101, 2015

Speciation of aluminium in mixtures of the ionic liquids [C3mpip][NTf2] and [C4mpyr][NTf2] with AlCl3: an electrochemical and NMR spectroscopy study. Chemistry 16(12): 3815-3826, 2010

Investigations of Molecular Interactions in Binary Mixtures of the Ionic Liquid [Emim][Bf4] and N-Methylaniline at Temperatures from 293.15 to 323.15K. Journal of Solution Chemistry 46(2): 281-304, 2017

Polarity, viscosity, and ionic conductivity of liquid mixtures containing [C4C1im][Ntf2] and a molecular component. Journal of Physical Chemistry. B 115(19): 6088-6099, 2011

Phase equilibria in ionic liquid-aromatic compound mixtures, including benzene fluorination effects. Journal of Physical Chemistry. B 113(21): 7631-7636, 2009

Ab initio study of EMIM-BF4 crystal interaction with a Li (100) surface as a model for ionic liquid/Li interfaces in Li-ion batteries. Journal of Chemical Physics 131(24): 244705, 2009

Thermal behaviour and tolerance to ionic liquid [emim]OAc in GH10 xylanase from Thermoascus aurantiacus SL16W. Extremophiles 18(6): 1023-1034, 2014

Molecular interactions in the ionic liquid emim acetate and water binary mixtures probed via NMR spin relaxation and exchange spectroscopy. Physical Chemistry Chemical Physics 16(17): 8078-8085, 2014

Surface-functionalized ionic liquid crystal-supported ionic liquid phase materials: ionic liquid crystals in mesopores. Chemphyschem 12(18): 3539-3546, 2011

Characterization of the phase behaviour of a novel polymerizable lyotropic ionic liquid crystal. Physical Chemistry Chemical Physics 17(35): 23059-23068, 2015

Identification of multiple conformers of the ionic liquid [emim][tf2n] in the gas phase using IR/UV action spectroscopy. Physical Chemistry Chemical Physics 18(25): 17037-17043, 2016