+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Multiple nitrene insertions into metal-sulfur bonds of dithiocarbamate complexes: synthesis of sulfido-amido and zwitterionic tetraamido complexes



Multiple nitrene insertions into metal-sulfur bonds of dithiocarbamate complexes: synthesis of sulfido-amido and zwitterionic tetraamido complexes



Dalton Transactions 2005(16): 2688-2695



The iodine(III) reagent, PhI[double bond, length as m-dash]NTs, acts as a source of the nitrene fragment NTs, which undergoes facile insertion into the metal-sulfur bonds of a range of dithiocarbamate complexes. Addition of two equivalents of PhI=NTs to [M(S(2)CNR2)2] affords sulfido-amido complexes [M{SC(NR2)SNTs}2](M=Ni, Cu), which insert two further nitrene fragments to afford zwitterionic tetraamido complexes [M{TsNSC(NR2)SNTs}2](M=Co, Ni, Cu). Crystallographic studies have been carried out on both types of complex allowing possible resonance hydrids of the new ligand types to be assessed.

Please choose payment method:






(PDF emailed within 0-6 h: $19.90)

Accession: 049638934

Download citation: RISBibTeXText

PMID: 16075107

DOI: 10.1039/b503004h


Related references

Efficient synthesis strategies by application of transition metal-catalyzed carbene/nitrene insertions into C-H bonds. Natural Product Reports 31(4): 449-455, 2014

Molybdenum sulfur complexes containing metal nitrogen multiple bonds. Abstracts of Papers American Chemical Society 182: INOR 196, 1981

Synthetic analogs of the active sites of iron sulfur proteins part 11 synthesis and properties of complexes containing the iron 2 sulfur core and the structures of bis o xylyl alpha alpha dithiolato mu sulfido ferrate iii and bis p tolylthiolato mu sulfido ferrate iii di anions. Journal of the American Chemical Society 97(5): 1032-1045, 1975

Reactivity of electrophilic micro-phosphinidene complexes with heterocumulenes: formation of the first sigma-pi-aminophosphaimine complexes [Mn2(CO)8{micro-eta1,eta2-P(NiPr2)=NR}] and diazoalkane insertions into metal-phosphorus bonds. Chemical Communications 2005(35): 4441-4443, 2005

Tunable N-substitution in zwitterionic benzoquinonemonoimine derivatives: metal coordination, tandemlike synthesis of zwitterionic metal complexes, and supramolecular structures. Chemistry 11(24): 7237-7246, 2005

Metal complexes of functionalized sulfur containing ligands iii. reactions of ph 3p 2pteta 2 c 2h 4 with acyclic and cyclic thiosulfinates platinum ii thiolato complexes with sulfenato ligands crystal structure determination of 4 sulfido 1 butanesulfenato s s' bis triphenylphosphane platinum ii ph 3p 2pt s0 ch 2 4 s. Chemische Berichte 125(5): 1047-1051, 1992

Transition metal complexes with sulfur ligands Part CXXV. Synthesis and characterization of hydrido and chloro complexes with rhodium sulfur cores. Inorganica Chimica Acta 272(1-2): 211-227, 1998

Transition Metal Complexes with Sulfur Ligands. 130.(1) Synthesis, Structure, and Reactivity of the Sulfur-Rich Ruthenium Hydride Complexes [Ru(H)(PR(3))('S(4)')](-) and the eta(2)-H(2) Complex [Ru(H(2))(PCy(3))('S(4)')] (R = Ph, (i)Pr, Cy; 'S(4)'(2-) = 1,2-Bis((2-mercaptophenyl)thio)ethane(2-)). Inorganic Chemistry 37(16): 3982-3988, 1998

Highly Stabilized Low-Spin Iron(III) and Cobalt(III) Complexes of a Tridentate Bis-Amide Ligand 2,6-Bis(N-phenylcarbamoyl)pyridine. Novel Nonmacrocyclic Tetraamido-N Coordination and Two Unusually Short Metal-Pyridine Bonds. Inorganic Chemistry 36(16): 3568-3572, 1997

The synthesis of new technetium complexes with metal nitrogen multiple bonds for use as imaging agents. Journal of Inorganic Biochemistry 43(2-3): 597-0, 1991

Molybdenum amido complexes with single Mo-N bonds: synthesis, structure, and reactivity. Chemistry 9(17): 4132-4143, 2003

Efficient synthesis of imino-methano Tröger bases by nitrene insertions into C-N bonds. Organic Letters 15(15): 3930-3933, 2013

On the paucity of molecular actinide complexes with unsupported metal-metal bonds: a comparative investigation of the electronic structure and metal-metal bonding in U2X6 (X = Cl, F, OH, NH2, CH3) complexes and d-block analogues. Inorganic Chemistry 45(17): 6828-6839, 2006

Transition metal complexes of the zwitterionic amino acid DL-methylsulfoniummethioninate and of the amido acid derived from it by facile amine deprotonation. Inorganica Chimica Acta 10: 215-220, 1974

Catalytic activity of metal complexes anchored to a solid support. 2. Synthesis of palladium complexes on amino-containing silica gels and their properties in the hydrogenation of C=C, CC, and C=N bonds. Russian Chemical Bulletin 28(1): 93-96, 1979