+ Site Statistics
+ Search Articles
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ PDF Full Text
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Translate
+ Recently Requested

Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins

Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins

Organic Letters 6(22): 4037-4039

[reaction: see text] Oxygen-promoted Pd(II) catalysis facilitated the synthesis of conjugated dienes by cross-coupling of alkenylboronic compounds and various olefins including highly substituted alkenes and cyclohexenone. Under mild conditions, these versatile reactions were efficient and highly stereoselective.

(PDF emailed within 0-6 h: $19.90)

Accession: 049839109

Download citation: RISBibTeXText

PMID: 15496093

DOI: 10.1021/ol0483192

Related references

Oxygen-promoted Pd(II) catalysis for the coupling of organoboron compounds and olefins. Organic Letters 5(13): 2231-2234, 2003

Oxidative palladium(II) catalysis: A highly efficient and chemoselective cross-coupling method for carbon-carbon bond formation under base-free and nitrogenous-ligand conditions. Journal of the American Chemical Society 128(50): 16384-16393, 2006

Nucleophile promoted gold redox catalysis with diazonium salts: C-Br, C-S and C-P bond formation through catalytic Sandmeyer coupling. Chemical Science 7(9): 6190-6196, 2018

Ligand-promoted oxidative cross-coupling of aryl boronic acids and aryl silanes by palladium catalysis. Angewandte Chemie 54(13): 4079-4082, 2015

Palladium(0)-catalyzed direct cross-coupling reaction of allylic alcohols with aryl- and alkenylboronic acids. Organic & Biomolecular Chemistry 6(16): 3005-3013, 2008

Palladium-Catalyzed Cross-Coupling of N-Sulfonylaziridines and Alkenylboronic Acids: Stereospecific Synthesis of Homoallylic Amines with Di- and Trisubstituted Alkenes. Organic Letters 19(7): 1738-1740, 2017

B-N, B-O, and B-CN Bond Formation via Palladium-Catalyzed Cross-Coupling of B-Bromo-Carboranes. Journal of the American Chemical Society 138(29): 9081-9084, 2016

CO2-promoted oxidative cross-coupling reaction for C-S bond formation via masked strategy in an odourless way. Chemical Communications 51(51): 10295-8, 2015

C-11-C bond formation by palladium-mediated cross-coupling of alkenylzirconocenes with methyl iodide. Journal of Labelled Compounds and Radiopharmaceuticals 49(2): 91-100, 2006

Palladium(II)-catalyzed dehydrogenative cross-coupling between two C(sp3)-H bonds: unexpected C=C bond formation. Angewandte Chemie 52(30): 7837-7840, 2013

Palladium catalyzed cross-coupling reactions for phosphorus-carbon bond formation. Chemical Society Reviews 33(4): 218-224, 2004

Ru(II)-Catalyzed Cross-Coupling of Cyclopropenes with Diazo Compounds: Formation of Olefins from two Different Carbene Precursors. Journal of Organic Chemistry, 2017

Palladium-catalyzed intramolecular reductive cross-coupling of Csp2-Csp3 bond formation. Chemistry 20(27): 8308-8313, 2014

Palladium-catalyzed C-C bond formation of arylhydrazines with olefins via carbon-nitrogen bond cleavage. Organic Letters 13(23): 6308-6311, 2011

Experimental and theoretical study on palladium-catalyzed C-P bond formation via direct coupling of triarylbismuths with P(O)-H compounds. Journal of Organic Chemistry 79(2): 608-617, 2014