+ Site Statistics
References:
54,258,434
Abstracts:
29,560,870
PMIDs:
28,072,757
+ Search Articles
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ PDF Full Text
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Translate
+ Recently Requested

Polysulfones: solid organic catalysts for the chemoselective cleavage of methyl-substituted allyl ethers under neutral conditions



Polysulfones: solid organic catalysts for the chemoselective cleavage of methyl-substituted allyl ethers under neutral conditions



Chemical Communications 2004(21): 2444-2445



The solid polysulfone made of SO2 and methylidenecyclopentane catalyzes the cleavage of methyl-substituted allyl ethers and liberates the corresponding alcohols.

(PDF emailed within 0-6 h: $19.90)

Accession: 049949854

Download citation: RISBibTeXText

PMID: 15514807

DOI: 10.1039/b410965a


Related references

Allyl, methallyl, prenyl, and methylprenyl ethers as protected alcohols: their selective cleavage with diphenyldisulfone under neutral conditions. Organic Letters 6(16): 2693-2696, 2004

Acetylation of aromatic ethers using acetic anhydride over solid acid catalysts in a solvent-free system. Scope of the reaction for substituted ethers. Organic and Biomolecular Chemistry 1(9): 1560-1564, 2003

UDCaT5: A Novel and Efficient Solid Superacid Catalyst for Claisen Rearrangement of Substituted Allyl Phenyl Ethers. Synthetic Communications 37(6): 941-946, 2007

Influence of hydrogen bonding in the activation of nucleophiles: PhSH-(catalytic) KF in N-methyl-2-pyrrolidone as an efficient protocol for selective cleavage of alkyl/aryl esters and aryl alkyl ethers under nonhydrolytic and neutral conditions. Journal of Organic Chemistry 67(8): 2541-2547, 2002

Catecholborane Reductive Cleavage of Allyl and Propargyl Acetals and Ketals: A Simple Route to Allyl and Prop-2-ynyl Ethers. Synthetic Communications 21(7): 907-913, 1991

Silane/iodine-based cleavage of esters and ethers under neutral conditions. Proceedings of the National Academy of Sciences of the United States of America 75(1): 4-6, 1978

Chemoselective and direct functionalization of methyl benzyl ethers and unsymmetrical dibenzyl ethers by using iron trichloride. Chemistry 20(9): 2631-2636, 2014

Synthesis of Substituted Quinazolone Allyl Ethers and allyl phenols and their effect on the oxidation of pyruvic acid by Rat Brain Homogenate. Advanced Synthesis & Catalysis 312(5): 958-963, 1970

Pincer-Nickel-Catalyzed Allyl-Aryl Coupling between Allyl Methyl Ethers and Arylzinc Chlorides. Journal of Organic Chemistry 80(24): 12627-12634, 2015

Nmr spectroscopy of naturally occurring phloroglucinol derivatives part 2 use of the additivity of substituent parameters in carbon 13 nmr spectral analysis of mono methyl and di methyl ethers of methyl substituted and acyl substituted phloroglucinols. Finnish Chemical Letters (8): 264-266, 1978

An Efficient and Chemoselective Cleavage of Prenyl Ethers with DDQ. Synlett 2002(03): 0507-0509, 2002

Application of a new phosphorus-free palladium heterogeneous nanocatalyst supported on modified MWCNT the highly selective and efficient cleavage of propargyl, allyl, and benzyl phenol ethers under mild conditions. Molecular Diversity 19(3): 481-500, 2016

Trapping Hemiacetals with Phosphono Substituted Palladium π-Allyl Complexes for the Synthesis of Substituted Cyclic Ethers. Tetrahedron Letters 56(23): 3534-3537, 2015

A novel cleavage of aryl benzyl ethers and allyl aryl ethers by sodium bis(2-methoxyethoxy)aluminum hydride. An alternative synthesis of pentazocine. Journal of Organic Chemistry 41(15): 2545-2548, 1976

Fluoroponytailed crown ethers and quaternary ammonium salts as solid-liquid phase transfer catalysts in organic synthesis. Topics in Current Chemistry 308: 213-232, 2011