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A Scandium Carbide Endohedral Metallofullerene: (Sc 2 C 2 )@C 84



A Scandium Carbide Endohedral Metallofullerene: (Sc 2 C 2 )@C 84



Angewandte Chemie 40(2): 397-399



Not Sc2 @C86 but Sc2 C2 @C84 : that is the conclusion of 13 C NMR spectroscopic and synchrotron X-ray powder diffraction studies on a new metallofullerene obtained by arc discharge of Sc2 O3 /graphite rods. The picture shows a schematic representation of the deduced structure, in which the novel scandium carbide cluster Sc2 C2 is encaged in D2d -C84 .

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Accession: 050028686

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PMID: 29712386

DOI: 10.1002/1521-3773(20010119)40:2<397::aid-anie397>3.0.co;2-3


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