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Rapid production of metal-organic frameworks via microwave-assisted solvothermal synthesis

Rapid production of metal-organic frameworks via microwave-assisted solvothermal synthesis

Journal of the American Chemical Society 128(38): 12394

This paper describes a very rapid technique for the production of metal-organic frameworks (MOF). The method uses a conventional microwave to nucleate crystal growth. A MOF synthesis that used to take hours or days can now be completed in 30 s to 2 min. The yield goes from approximately 30% to over 90%. Novel MOFs can be made, since the growth process is no longer dependent on the walls or dust particles for nucleation. Particle sizes have a narrower distribution. Further, the particle size can be controlled by varying the precursor concentration.

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Accession: 050113123

Download citation: RISBibTeXText

PMID: 16984171

DOI: 10.1021/ja0635231

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