EurekaMag.com logo
+ Site Statistics
References:
53,623,987
Abstracts:
29,492,080
+ Search Articles
+ Subscribe to Site Feeds
EurekaMag Most Shared ContentMost Shared
EurekaMag PDF Full Text ContentPDF Full Text
+ PDF Full Text
Request PDF Full TextRequest PDF Full Text
+ Follow Us
Follow on FacebookFollow on Facebook
Follow on TwitterFollow on Twitter
Follow on LinkedInFollow on LinkedIn

+ Translate

(2R*,4R*,7S*,10R*,12R*)-3,11,13,15-Tetra-oxa-penta-cyclo-[5.5.3.0(1,7).0(2,4).0(10,12)]penta-deca-5,8-dien-14-one



(2R*,4R*,7S*,10R*,12R*)-3,11,13,15-Tetra-oxa-penta-cyclo-[5.5.3.0(1,7).0(2,4).0(10,12)]penta-deca-5,8-dien-14-one



Acta Crystallographica. Section E, Structure Reports Online 69(Pt 10): O1504-5



The title compound, C11H8O5, features a 'skipped' diene, an anti-bis-(epoxide) and a cyclic carbonate, all embedded in a densely functionalized [4.4.3]propellane scaffold. The crystal packing of this diepoxide is effected primarily by C-H⋯O hydrogen bonds, which link the mol-ecules into tapes along the b axis. Inter-tape connectivity is brought about by centrosymmetrically disposed pairs of C⋯O contacts [3.183 (4) Å] between the C(δ+)=O(δ-) dipoles of neighbouring carbonate moieties.

(PDF emailed within 0-6 h: $19.90)

Accession: 051018553

Download citation: RISBibTeXText

PMID: 24098200

DOI: 10.1107/S1600536813023817



Related references

1-Dimethyl-silyl-2-phenyl-3-(η-tetra-methyl-cyclo-penta-dien-yl)-prop-1-en-1-yl-κC](η-penta-methyl-cyclo-penta-dien-yl)titanium(III). Acta Crystallographica. Section E, Structure Reports Online 65(Pt 11): M1481-M1481, 2009

(1S*,3S*,8S*,10S*)-10-Fluoro-15-oxa-tetra-cyclo-[6.6.1.0.0]penta-deca-5,12-dien-3-ol. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 8): O1985-O1985, 2011

Bis[1,2-bis-(meth-oxy-carbon-yl)ethene-1,2-dithiol-ato-κ(2) S,S']bis-(η(5)-penta-methyl-cyclo-penta-dien-yl)tetra-μ3-sulfido-tetra-iron(4 Fe-Fe) hexa-fluoridophosphate. Acta Crystallographica. Section E, Structure Reports Online 69(Pt 4): M227-M228, 2013

Bis(η(5)-penta-methyl-cyclo-penta-dien-yl)aluminium tetra-bromido-aluminate. Acta Crystallographica. Section E, Structure Reports Online 70(Pt 3): M88-M89, 2014

(η-Benzophenone)(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) tetra-phenyl-borate. Acta Crystallographica. Section E, Structure Reports Online 65(Pt 11): M1486-M1486, 2009

Acetonitrile-dicarbon-yl(η-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluorido-borate. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 7): M924-M924, 2011

(η-Penta-methyl-cyclo-penta-dien-yl)(η-p-toluene-sulfonamide)ruthenium(II) tetra-phenyl-borate. Acta Crystallographica. Section E, Structure Reports Online 64(Pt 12): M1568-M1568, 2008

Bis[bis-(penta-methyl-cyclo-penta-dien-yl)cobalt(III)] tetra-chlorido-cobaltate(II) di-chloro-methane disolvate. Acta Crystallographica. Section E, Structure Reports Online 69(Pt 9): M504-M504, 2014

Dicarbon-yl(hexa-methyl-ene-1,3,5,7-tetra-mine-κN(1))(η(5)-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluoridoborate. Acta Crystallographica. Section E, Structure Reports Online 68(Pt 7): M931-M931, 2012

μ-Oxido-bis-{bis-[(penta-fluoro-phen-yl)methano-lato](η-penta-methyl-cyclo-penta-dien-yl)titanium(IV)}. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 8): M1104-M1104, 2011

μ-Oxido-bis-[bis-(penta-fluoro-phenolato)(η-penta-methyl-cyclo-penta-dien-yl)titanium(IV). Acta Crystallographica. Section E, Structure Reports Online 67(Pt 8): M1147-M1147, 2011

2-Methyl-6-(4,4,10,13,14-penta-methyl-3-oxo-2,3,4,5,6,7,10,11,12,13,14,15,16,17-tetra-deca-hydro-1H-cyclo-penta-[a]phenanthren-17-yl)hept-2-enoic acid. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 3): O711-O711, 2011

Crystal structure of μ-oxido-1,1'κ(2) O:O-bis{tetra-μ-oxido-1:2κ(2) O:O;1:3κ(2) O:O;2:3κ(4) O:O-tris[1,2,3(η(5))-penta-methyl-cyclo-penta-dien-yl]-trianglo-trititanium(IV)}. Acta Crystallographica. Section E, Crystallographic Communications 71(Pt 4): M97-M97, 2015

(η-Isopropyl N-phenyl-carbamate)(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) tetra-phenyl-borate acetone monosolvate. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 9): M1231-M1231, 2011

Bis[1,2-bis-(eth-oxy-carbon-yl)ethene-1,2-dithiol-ato-κ(2) S,S']bis-(η(5)-penta-methyl-cyclo-penta-dien-yl)tetra-μ3-sulfido-diiron(IV)diiron(III)(3 Fe-Fe). Acta Crystallographica. Section E, Structure Reports Online 69(Pt 4): M181-M181, 2013