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(Dimethyl-formamide-κO)(2-hy-droxy-benzoato-κO,O)[tris-(1-methyl-1H-benzimidazol-2-ylmethyl-κN)amine-κN]manganese(II) perchlorate dimethyl-formamide monosolvate



(Dimethyl-formamide-κO)(2-hy-droxy-benzoato-κO,O)[tris-(1-methyl-1H-benzimidazol-2-ylmethyl-κN)amine-κN]manganese(II) perchlorate dimethyl-formamide monosolvate



Acta Crystallographica. Section E, Structure Reports Online 66(Pt 10): M1252



In the title complex, [Mn(C(7)H(5)O(3))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is coordinated in a slightly distorted monocapped trigonal-prismatic geometry. The tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine (Mentb) ligand coordinates in a tetra-dentate mode and the coordination is completed by a bis-chelating salicylate ligand and a dimethyl-formamide ligand. The hy-droxy group and the ortho H atoms of the salicylate ligand were refined as disordered over two sites with occupancies of 0.581 (8) and 0.419 (8). Both disorder components of the hy-droxy group form intra-molecular O-H⋯O hydrogen bonds.

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Accession: 051019678

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PMID: 21587401


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