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A Sn(IV)-porphyrin-based metal-organic framework for the selective photo-oxygenation of phenol and sulfides

A Sn(IV)-porphyrin-based metal-organic framework for the selective photo-oxygenation of phenol and sulfides

Inorganic Chemistry 50(12): 5318-5320

A functional tin(IV)-porphyrin derivative was used as a building block to construct a novel 3D porous metal-organic framework (MOF). The MOF is built up from tin(IV)-porphyrin struts linking up Zn atoms and formates joining Sn(IV) centers. The immobilization of the photoactive Sn-porphyrins in the channel walls lets the MOF present remarkable photocatalytic activities for the oxygenation of phenol and sulfides, resulting in excellent yields and remarkable selectivity in heterogeneous phases.

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Accession: 051075980

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PMID: 21568275

DOI: 10.1021/ic200295h

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