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A novel copper containing photoinitiator, copper(II) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization



A novel copper containing photoinitiator, copper(II) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization



Chemical Communications 49(72): 7950-7952



A novel copper(II) complex has been developed in which the counter anion, acylphosphinate, serves as a visible light photoinitiator. This molecule is inactive in the dark but, upon visible light exposure, both CuAAC and ATRP reactions are readily and rapidly initiated.

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Accession: 051193228

Download citation: RISBibTeXText

PMID: 23900488

DOI: 10.1039/c3cc43637c


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