+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Compounds with low-valent group 13 metals as ligands for electron poor main group and transition metals

Compounds with low-valent group 13 metals as ligands for electron poor main group and transition metals

Dalton Transactions 2009(11): 1887-1893

The application of low-valent group 13 metal compounds as ligands in coordination chemistry results in the formation of new metal-to-metal bonds. Traditionally, the coordination chemistry of these compounds was focused on late transition metals. This article now reviews recent progress of the coordination chemistry of compounds with low-valent group 13 metals in the chemistry of electron poor main group and transition metal as well as in f-block elements.

Please choose payment method:

(PDF emailed within 0-6 h: $19.90)

Accession: 052269457

Download citation: RISBibTeXText

PMID: 19259555

DOI: 10.1039/b816377d

Related references

Chemical detection of carbon-metal bonds: From distinct sigma-bonding of main-group metals to ambiguous pi-bonding with transition metals. Inorganica Chimica Acta 364(1): 3-9, 2010

Applications of bis(1-R-imidazol-2-yl)disulfides and diselenides as ligands for main-group and transition metals: kappa2-(N,N) coordination, S-S bond cleavage, and S-S/E-E (E = S, Se) bond metathesis reactions. Inorganic Chemistry 46(22): 9234-9244, 2007

1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes as strong salt-free reductants for generating low-valent early transition metals with electron-donating ligands. Journal of the American Chemical Society 136(13): 5161-5170, 2014

Relation between the ctalytic activity of binary compounds of group II metals with nonmetals and the positions of the elements in Mendeleev's periodic system Communication 2: Catalytic decomposition of isopryopyk alcohol over oxides of group IIB metals. Russian Chemical Bulletin 6(4): 431-439, 1957

Rings, Polymers, and New Materials Containing Phosphorus and Other Main Group Main Elements or Transition Metals. Phosphorus Sulfur and Silicon and the Related Elements 76(1-4): 219-222, 1993

Design of new heteroscorpionate ligands and their coordinative ability toward Group 4 transition metals; an efficient synthetic route to obtain enantiopure ligands. Dalton Transactions 2006(36): 4359-4370, 2006

Polynuclear complexes of main group and transition metals with polyaminopolycarboxylate and polyoxometalate. Dalton Transactions 41(33): 9971-9978, 2012

Porphyrin complexes of the period 6 main group and late transition metals. Dalton Transactions 40(25): 6591-6609, 2011

Alkyl Shifts between Transition Metals and Coordinated Main Group Atoms. Helvetica Chimica Acta 67(1): 1-17, 1984

Some Typical Properties of Cages Containing Simultaneously Main Group Metals and Non-Metals. Phosphorus Sulfur and Silicon and the Related Elements 41(1-2): 195-221, 1989

L-edge x-ray-absorption systematics of the noble metals Rh, Pd, and Ag and the main-group metals In and Sn: A study of the unoccupied density of states in 4d elements. Physical Review. B, Condensed Matter 31(4): 1888-1902, 1985

Chemical safety data sheets vol 2 main group metals and their compounds. Allen, R Chemical Safety Data Sheets, Vol 2 Main Group Metals And Their Compounds Xvi+419p Royal Society Chemistry: Cambridge, England, Uk; Crc Press Inc : Boca Raton, Florida, Usa Illus Paper Xvi+419p, 1990

X-ray-absorption studies of the d-orbital occupancies of selected 4d/5d transition metals compounded with group-III/IV ligands. Physical Review. B, Condensed Matter 50(10): 6555-6563, 1994

Chemical bonding in phosphane and amine complexes of main group elements and transition metals. Inorganic Chemistry 45(17): 6956-6964, 2006

Sandwich-like compounds based on the all-metal aromatic unit Al(4)2- and the main-group metals M (M=Li, Na, K, Be, Mg, Ca). Chemistry 13(9): 2546-2555, 2006