+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Dibromido[1,1'-dibenzyl-2,2'-(sulfane-diyl-dimethyl-ene)di-1H-benzimidazole]-cadmium(II) dimethyl-formamide solvate



Dibromido[1,1'-dibenzyl-2,2'-(sulfane-diyl-dimethyl-ene)di-1H-benzimidazole]-cadmium(II) dimethyl-formamide solvate



Acta Crystallographica. Section E Structure Reports Online 66(Pt 8): M993



In the title compound, [CdBr(2)(C(30)H(26)N(4)S)]·C(3)H(7)NO, both the complex and solvent mol-ecule lie on a crystallographic mirror plane. The Cd(II) ion is coordinated in a disorted square-pyramidal CdBr(2)N(2)S environment with one of the Br atoms in the apical site. In the crystal structure, the benzimidazole ring systems are involved in weak inter-molecular π-π stacking inter-actions [centroid-centroid distances = 3.606 (2) and 3.753 (2) Å]. Further stabilization is provided by weak inter-molecular C-H⋯O hydrogen bonds. The methyl H atoms of the dimethyl-formamide solvent mol-ecule are disordered about a mirror plane.

Please choose payment method:






(PDF emailed within 0-6 h: $19.90)

Accession: 052592575

Download citation: RISBibTeXText

PMID: 21588213

DOI: 10.1107/s1600536810028448


Related references

Diaqua-bis(N,N'-dibenzyl-ethane-1,2-diamine-κN,N')nickel(II) dichloride N,N-dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 65(Pt 12): M1526, 2009

(Dimethyl-formamide-κO){4,4',6,6'-tetra-bromo-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 65(Pt 7): M758, 2009

(3,5-Dichloro-salicylaldehyde thio-semi-carbazonato-κS,N,O)(N,N'-dimethyl-formamide-κO)copper(II) dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 64(Pt 5): M633-M634, 2008

Dichloridobis[5-nitro-1-trimethyl-silyl-methyl-1H-benzimidazole-κN]cobalt(II) N,N-dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 66(Pt 3): M253-M254, 2010

(Dimethyl-formamide)(2-methyl-propen-oato)[tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine]-manganese(II) perchlorate dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 66(Pt 10): M1270, 2010

8,8-Dimethyl-5-(4-methyl-phen-yl)-8,9-dihydro-pyrimido[4,5-b]quinoline-2,4,6(1H,3H,7H)-trione N,N-dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 64(Pt 3): O606, 2008

Dichlorido{μ-6,6'-dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 64(Pt 11): M1460, 2008

Dibromido(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')(dimethyl sulfoxide-κO)cadmium. Acta Crystallographica. Section E Structure Reports Online 68(Pt 7): M1006, 2012

Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N')(dimethyl sulfoxide-κO)cadmium. Acta Crystallographica. Section E Structure Reports Online 69(Pt 1): M49, 2013

Poly[[aqua-(μ(4)-1H-benzimidazole-5,6-dicarboxyl-ato-κN:O:O:O)(N,N-dimethyl-formamide-κO)cadmium(II)] dihydrate. Acta Crystallographica. Section E Structure Reports Online 66(Pt 2): M209-M210, 2010

(4,4'-Dimethyl-2,2'-bipyridine-κ(2) N,N')(dimethyl-formamide-κO)diiodido-cadmium. Acta Crystallographica. Section E Structure Reports Online 68(Pt 12): M1495, 2012

Acetoguanamine N,N-dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 64(Pt 9): O1685, 2008

2,2'-(Quinoxaline-2,3-di-yl)diphenol dimethyl-formamide solvate. Acta Crystallographica. Section E Structure Reports Online 66(Pt 2): O395, 2010

Effects of dimethyl sulphoxide, dimethyl formamide and dimethyl acetamide on myocardial contractility and enzyme activity. Life Sciences 8(23): 1325-1335, 1969