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Extended potential-gradient architecture of a phenylazomethine dendrimer



Extended potential-gradient architecture of a phenylazomethine dendrimer



Organic Letters 15(8): 1810-1813



A dendritic nanoshell based on rigid phenylazomethine units was synthesized up to fifth generation around a zinc porphyrin core. Due to the finely organized sparse architecture, accessibility to the core can be discriminated by the size of the molecules and ionic species. By using this function, the lifetime of the photochemically produced radical ion pair can be extended over 200 times longer along with a good quantum yield.

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Accession: 053161421

Download citation: RISBibTeXText

PMID: 23570458

DOI: 10.1021/ol4003493


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