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Facile synthesis of brush poly(phosphoamidate)s via one-pot tandem ring-opening metathesis polymerization and atom transfer radical polymerization



Facile synthesis of brush poly(phosphoamidate)s via one-pot tandem ring-opening metathesis polymerization and atom transfer radical polymerization



Macromolecular Rapid Communications 35(17): 1509-1515



Poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA)-based brush poly(phosphoamidate)s are successfully synthesized by a combination of ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) following either a commutative two-step procedure or a straightforward one-pot process using Grubbs ruthenium-based catalysts for tandem catalysis. Compared with the traditional polymerization method, combining ROMP and ATRP in a one-pot process allows the preparation of brush copolymers characterized by a relatively moderate molecular weight distribution and quantitative conversion of monomer. Moreover, the surface morphologies and aggregation behaviors of these polymers are studied by AFM and TEM measurements.

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Accession: 053187430

Download citation: RISBibTeXText

PMID: 24729161

DOI: 10.1002/marc.201400050


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