+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Gold(I)-catalyzed intramolecular hydroarylation of allenes



Gold(I)-catalyzed intramolecular hydroarylation of allenes



Journal of Organic Chemistry 73(6): 2439-2441



Gold(I) complexes react with 4-allenyl arenes in an exo fashion to furnish vinyl-substituted benzocycles. Phosphite gold(I) monocations were found to be optimal, and the catalyst was tolerant of ethers, esters, and pyrroles. Reactions proceeded in unpurified solvent at room temperature.

Please choose payment method:






(PDF emailed within 0-6 h: $19.90)

Accession: 053432741

Download citation: RISBibTeXText

PMID: 18278940

DOI: 10.1021/jo7024948


Related references

Gold(I)-catalyzed intramolecular enantioselective hydroarylation of allenes with indoles. Organic Letters 9(10): 1935-1938, 2007

Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes. Angewandte Chemie 48(31): 5733-5736, 2009

Gold(I)-Catalyzed Hydroarylation of Allenes with Indoles. Journal of Organometallic Chemistry 694(4): 571-575, 2009

Gold(I)-catalyzed intermolecular hydroarylation of allenes with nucleophilic arenes: scope and limitations. Tetrahedron 65(9): 1785-1789, 2009

Gold(I)-catalyzed enantioselective intermolecular hydroarylation of allenes with indoles and reaction mechanism by density functional theory calculations. Chemistry An Asian Journal 6(3): 812-824, 2011

A concise route to indoloazocines via a sequential Ugi-gold-catalyzed intramolecular hydroarylation. Chemical Communications 48(52): 6550-6552, 2012

Intramolecular hydroarylation of alkynes catalyzed by platinum or gold: mechanism and endo selectivity. Chemistry 11(10): 3155-3164, 2005

The mechanism and regioselectivity of gold(I) or platinum(II) catalyzed intramolecular hydroarylation to pyrrolopyridinones and pyrroloazepinones. Organic and Biomolecular Chemistry 12(42): 8433-8441, 2014

Gold(I)-catalyzed intramolecular enantioselective hydroalkoxylation of allenes. Angewandte Chemie 46(1-2): 283-285, 2007

Gold(I)-catalyzed enantioselective intramolecular hydroamination of allenes. Journal of the American Chemical Society 129(9): 2452-2453, 2007

Gold-catalyzed hydroarylation of allenes: a highly regioselective carbon-carbon bond formation producing six-membered rings. Organic Letters 9(23): 4821-4824, 2007

Synthesis of functionalized indolizines via gold(i)-catalyzed intramolecular hydroarylation/aromatization of pyrrole-ynes. Organic and Biomolecular Chemistry 15(38): 8119-8133, 2017

Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes with Ureas. Journal of Organometallic Chemistry 696(1): 316-320, 2011

Gold versus silver catalyzed intramolecular hydroarylation reactions of [(3-arylprop-2-ynyl)oxy]benzene derivatives. Organic and Biomolecular Chemistry 10(48): 9700-9708, 2012

Enantioselective Synthesis of Fully Benzenoid Single and Double Carbohelicenes via Gold-Catalyzed Intramolecular Hydroarylation. Chemistry 24(21): 5434-5438, 2018