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Gold(I)-catalyzed intramolecular hydroarylation of allenes

Gold(I)-catalyzed intramolecular hydroarylation of allenes

Journal of Organic Chemistry 73(6): 2439-2441

Gold(I) complexes react with 4-allenyl arenes in an exo fashion to furnish vinyl-substituted benzocycles. Phosphite gold(I) monocations were found to be optimal, and the catalyst was tolerant of ethers, esters, and pyrroles. Reactions proceeded in unpurified solvent at room temperature.

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Accession: 053432741

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PMID: 18278940

DOI: 10.1021/jo7024948

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