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Hexa-kis-(dimethyl-formamide-κO)manganese(II) (dimethyl-formamide-κO)pentakis(-thio-cyanato--κN)chromate(III)



Hexa-kis-(dimethyl-formamide-κO)manganese(II) (dimethyl-formamide-κO)pentakis(-thio-cyanato--κN)chromate(III)



Acta Crystallographica. Section E Structure Reports Online 68(Pt 6): M823



The title compound, [Mn(C(3)H(7)NO)(6)][Cr(NCS)(5)(C(3)H(7)NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hy-droxy-eth-yl)tetra-zole as starting materials. The crystal structure of the complex consists of an [Mn(dmf)(6)](2+) cation and a [Cr(NCS)(5)(dmf)](2-) anion (dmf = dimethyl-formamide). The Mn(II) and Cr(III) atoms show a slightly distorted octa-hedral MnO(6) and CrN(5)O coordination geometries with adjacent angles in the range 85.29 (13)-95.96 (14)°.

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Accession: 053528742

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PMID: 22719365

DOI: 10.1107/s1600536812023069


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