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Hexakis(N,N-dimethyl-formamide-κO)cobalt(II) bis-(perchlorate)



Hexakis(N,N-dimethyl-formamide-κO)cobalt(II) bis-(perchlorate)



Acta Crystallographica. Section E, Structure Reports Online 66(Pt 3): M279



The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl-formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol-ecules of DMF in a slightly distorted octa-hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C-H⋯O hydrogen-bonding inter-actions.

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Accession: 053529013

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PMID: 21580225

DOI: 10.1107/s160053681000454x


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