+ Site Statistics
References:
54,258,434
Abstracts:
29,560,870
PMIDs:
28,072,757
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Highly efficient vinylaromatics generation via iron-catalyzed sp3 C-H bond functionalization CDC reaction: a novel approach to preparing substituted benzo[α]phenazines



Highly efficient vinylaromatics generation via iron-catalyzed sp3 C-H bond functionalization CDC reaction: a novel approach to preparing substituted benzo[α]phenazines



Chemical Communications 48(98): 11993-5



An iron-catalyzed benzylic vinylation was developed to transfer the carbon atom in the N,N-dimethyl moiety of N,N-dimethylacetamide (or N,N-dimethylformamide) to 2-methyl azaarenes to generate 2-vinyl azaarenes.

Please choose payment method:






(PDF emailed within 0-6 h: $19.90)

Accession: 053557512

Download citation: RISBibTeXText

PMID: 23128502

DOI: 10.1039/c2cc36708d


Related references

Iron-catalyzed aerobic difunctionalization of alkenes: a highly efficient approach to construct oxindoles by C-S and C-C bond formation. Chemical Communications 50(31): 4115-4118, 2014

Iron(III)-catalyzed and air-mediated tandem reaction of aldehydes, alkynes and amines: an efficient approach to substituted quinolines. Chemistry 15(26): 6332-6334, 2009

Highly efficient copper-catalyzed nitro-Mannich type reaction: cross-dehydrogenative-coupling between sp3 C-H bond and sp3 C-H bond. Journal of the American Chemical Society 127(11): 3672-3673, 2005

Copper-catalyzed B-H bond insertion reaction: a highly efficient and enantioselective C-B bond-forming reaction with amine-borane and phosphine-borane adducts. Journal of the American Chemical Society 135(38): 14094-7, 2013

Iron-catalyzed C(sp3)-C(sp3) bond formation through C(sp3)-H functionalization: a cross-coupling reaction of alcohols with alkenes. Angewandte Chemie 48(46): 8761-8765, 2009

C(sp3)-H Bond Functionalization of Benzo[c]oxepines via C-O bond Cleavage: Formal [3+3] Synthesis of Multi-Substituted Chromans. Journal of Organic Chemistry: -, 2018

H(3)PW(12)O(40)-catalyzed multicomponent reaction for efficient synthesis of highly substituted piperidines. Combinatorial Chemistry & High Throughput Screening 17(6): 503-508, 2015

A NEW APPROACH TO THE SYNTHESIS OF SUBSTITUTED PHENAZINES VIA PALLADIUM-CATALYZED ARYL LIGATION i.. Heterocycles 84(2): -, 2012

Palladium-catalyzed intramolecular asymmetric C-H functionalization/cyclization reaction of metallocenes: an efficient approach toward the synthesis of planar chiral metallocene compounds. Journal of the American Chemical Society 136(12): 4472-4475, 2014

Iron-catalyzed oxidative direct α-C-H bond functionalization of cyclic ethers: selective C-O bond formation in the presence of a labile aldehyde group. Organic Letters 16(7): 1912-1915, 2014

Novel silver tetrafluoroborate catalyzed electrophilic cascade cyclization reaction: a facile approach to the synthesis of halo-substituted benzo[a]fluorenols. Organic Letters 14(14): 3588-3591, 2012

Gold(III)- and platinum(II)-catalyzed domino reaction consisting of heterocyclization and 1,2-migration: efficient synthesis of highly substituted 3(2H)-furanones. Angewandte Chemie 45(35): 5878-5880, 2006

Silver-Catalyzed Cascade Radical Cyclization: A Direct Approach to 3,4-Disubstituted Dihydroquinolin-2(1H)-ones through Activation of the P-H Bond and Functionalization of the C(sp(2))-H Bond. Journal of Organic Chemistry 81(5): 2122-2127, 2016

Efficient synthesis of highly substituted pyrroles through a Pd(OCOCF3)2-catalyzed cascade reaction of 2-alkenal-1,3-dicarbonyl compounds with primary amines. Chemical Communications 49(41): 4667-4669, 2013

Tandem Gold(III)-Catalyzed Amination-Intramolecular Hydroamination Reactions of 1-En-4-yn-3-ols with Sulfonamides: Efficient Approach to Highly Substituted Pyrroles. Advanced Synthesis & Catalysis 350(2): 243-248, 2008